Toward Coordination Polymers Based on Fine-Tuneable Group 13 Organometallic Phthalates

Inorg. Chem. 2014, 53, 7270-7275.

 

Toward Coordination Polymers Based on Fine-Tuneable Group 13 Organometallic Phthalates

Iwona Justyniak,*a Wojciech Bury,b Daniel Prochowicz,b Katarzyna Wójcik,a Janusz Zachara,b and Janusz Lewiński*ab

a Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw, Poland
b Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw, Poland

DOI: 10.1021/ic5005598
First published online 27 Jun 2014

A homologue series of group 13 organometallic macrocyclic phthalates [(MMe2)2(μ-O2C)2-1,2-C6H4]2 (where M = Al, Ga, In) was investigated as potential molecular building blocks for crystal engineering of extended metal−organic structures. Reactions of these molecular carboxylates with various monodentate Lewis bases provide the first examples of group 13 organometallic coordination polymers based on a dicarboxylate unit.

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