{"id":4275,"date":"2017-03-01T17:24:21","date_gmt":"2017-03-01T16:24:21","guid":{"rendered":"http:\/\/lewin.ch.pw.edu.pl\/?p=4275"},"modified":"2017-04-06T13:06:35","modified_gmt":"2017-04-06T12:06:35","slug":"of-a-magnetically-active-mononuclear-chiral-mniii-complex","status":"publish","type":"post","link":"https:\/\/lewin.ch.pw.edu.pl\/?p=4275","title":{"rendered":"Magnetically-active mononuclear chiral Mn(III) complex"},"content":{"rendered":"
European Journal of Inorganic Chemistry 2017<\/b>, 1392\u20131395.<\/div>\n

 <\/p>\n

Synthesis, structure and magnetic properties of a mononuclear chiral bis-aminoalkoxide(acetate)Mn(III) complex<\/h1>\n


\nArkadiusz Kornowicz<\/a>,a<\/sup> Micha\u0142 Terlecki<\/a>,a<\/sup>Daniel Prochowicz<\/a>,b<\/sup> C\u00e9line Pichon,c,d<\/sup> Iwona Justyniak<\/a>,b<\/sup> Wojciech Bury<\/a>,e<\/sup> Zbigniew Wr\u00f3bel<\/a>,b<\/sup> Jean-Pascal Sutter,c,d<\/sup> Janusz Lewi\u0144ski<\/a>,a,b<\/sup><\/strong><\/p>\n

a <\/sup>Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw, Poland
\nb <\/sup>Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44\/52, 01-224 Warsaw, Poland
\nc <\/sup>CNRS ; LCC (Laboratoire de Chimie de Coordination); 205, route de Narbonne, F-31077 Toulouse, France
\nd <\/sup>Universit\u00e9 de Toulouse; UPS, INPT; LCC; F-31077 Toulouse, France
\ne <\/sup>Faculty of Chemistry, University of Wroc\u0142aw, F. Joliot-Curie 14, 50-383 Wroc\u0142aw, Poland<\/p>\n

DOI: <\/strong> 10.1002\/ejic.201700084
\nFirst published online 24 Feb 2017.
\nPaper on the publisher\u2019s website.<\/a><\/p>\n

<\/p>\n

A new synthetic procedure was developed to obtain a novel mononuclear chiral square pyramidal
\nbis-aminoalkoxide(acetate)Mn(III) complex from a heterometallic Zn(II)\/Mn(II) system, with a crucial role for O2 in the process. The complex was characterized spectroscopically and crystallographically, and its magnetic properties were determined. The Mn(III) ion exhibit the magnetic anisotropy with ZFS parameter D = \u20132.95cm-1<\/sup>.<\/p>\n","protected":false},"excerpt":{"rendered":"

European Journal of Inorganic Chemistry 2017, 1392\u20131395.   Synthesis, structure and magnetic properties of a mononuclear chiral bis-aminoalkoxide(acetate)Mn(III) complex Arkadiusz Kornowicz,a Micha\u0142 Terlecki,aDaniel Prochowicz,b C\u00e9line Pichon,c,d Iwona Justyniak,b Wojciech Bury,e Zbigniew Wr\u00f3bel,b Jean-Pascal Sutter,c,d Janusz Lewi\u0144ski,a,b a Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw, Poland b Institute of Physical Chemistry, Polish […]<\/p>\n","protected":false},"author":2,"featured_media":4276,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"inline_featured_image":false,"footnotes":""},"categories":[19],"tags":[],"class_list":["post-4275","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-paper"],"_links":{"self":[{"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/posts\/4275","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=4275"}],"version-history":[{"count":7,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/posts\/4275\/revisions"}],"predecessor-version":[{"id":4370,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/posts\/4275\/revisions\/4370"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/media\/4276"}],"wp:attachment":[{"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=4275"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=4275"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=4275"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}