{"id":3377,"date":"2015-02-26T17:22:58","date_gmt":"2015-02-26T16:22:58","guid":{"rendered":"http:\/\/lewin.ch.pw.edu.pl\/?p=3377"},"modified":"2015-03-30T16:20:07","modified_gmt":"2015-03-30T15:20:07","slug":"tert-butyltert-butoxyzinc-hydroxides-hybrid-models-for-single-source-precursors-of-zno-nanocrystals","status":"publish","type":"post","link":"https:\/\/lewin.ch.pw.edu.pl\/?p=3377","title":{"rendered":"Hybrid Models for Single Source Precursors of ZnO Nanocrystals"},"content":{"rendered":"
Chem. Eur. J.<\/i>, 2015<\/b>, 21<\/i>, 5488\u20135495.<\/div>\n
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<\/div>\n

 <\/p>\n

tert-Butyl(tert-Butoxy)zinc Hydroxides: Hybrid Models for Single Source Precursors of ZnO Nanocrystals<\/span><\/strong><\/div>\n

Kamil Soko\u0142owski<\/a>,a<\/sup>\u00a0\u00a0Iwona Justyniak<\/a>,a<\/sup>\u00a0 Wojciech Bury<\/a>,b<\/sup>\u00a0\u00a0 Justyna Grzonka,c<\/sup>\u00a0Zbigniew Kaszkur,a<\/sup> \u0141ukasz M\u0105kolski<\/a>,b<\/sup>\u00a0\u00a0 Micha\u0142 Dutkiewicz,b<\/sup>\u00a0 Agnieszka Lewalska,b<\/sup> Dominik Kubicki<\/a>,b<\/sup>\u00a0\u00a0 Katarzyna W\u00f3jcik<\/a>,a<\/sup>\u00a0 Krzysztof Kurzyd\u0142owski<\/a>c<\/sup> and\u00a0 Janusz Lewi\u0144ski<\/a>*a<\/sup>b<\/sup><\/strong><\/p>\n

a\u00a0<\/sup>Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44\/52, 01-224 Warsaw, Poland<\/em>
\nb\u00a0<\/sup>Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw, Poland<\/em>
\nc\u00a0<\/sup>Faculty of Materials Science and Engineering, Warsaw University of Technology, Wo\u0142oska 141, 02-507 Warsaw, Poland.<\/em><\/p>\n

DOI: <\/strong> 10.1002\/chem.201406245
\nFirst published online 16 Feb 2015<\/p>\n

Alkylzinc alkoxides, [RZnOR\u2032]4<\/sub>, have received much attention as efficient precursors of ZnO nanocrystals (NCs), and their \u201cZn4<\/sub>O4<\/sub>\u201d heterocubane core has been regarded as a \u201cpreorganized ZnO\u201d. A comprehensive investigation of the synthesis and characterization of a new family of tert-butyl(tert-butoxy)zinc hydroxides, [(t<\/sup>Bu)4<\/sub>Zn4<\/sub>(\u03bc3<\/sub>-Ot<\/sup>Bu)x<\/sub>(\u03bc3<\/sub>-OH)4\u2212x<\/sub>], as model single-source precursors of ZnO NCs is reported. The direct reaction between well-defined [t<\/sup>BuZnOH]6<\/sub> (16<\/sub><\/b>) and [t<\/sup>BuZnOt<\/sup>Bu]4<\/sub> (24<\/sub><\/b>) in various molar ratios allows the isolation of new mixed cubane aggregates as crystalline solids in a high yield: [(t<\/sup>Bu)4<\/sub>Zn4<\/sub>(\u03bc3<\/sub>-Ot<\/sup>Bu)3<\/sub>(\u03bc3<\/sub>-OH)] (3<\/b>), [(t<\/sup>Bu)4<\/sub>Zn4<\/sub>(\u03bc3<\/sub>-Ot<\/sup>Bu)2<\/sub>(\u03bc3<\/sub>-OH)2<\/sub>] (4<\/b>), [(t<\/sup>Bu)4<\/sub>Zn4<\/sub>(\u03bc3<\/sub>-Ot<\/sup>Bu)(\u03bc3<\/sub>-OH)3<\/sub>] (5<\/b>). The resulting products were characterized in solution by 1<\/sup>H\u2005NMR and IR spectroscopy, and in the solid state by single-crystal X-ray diffraction. The thermal transformations of 2\u20135<\/b> were monitored by in situ<\/i> variable-temperature powder X-ray diffraction and thermogravimetric measurements. The investigation showed that the Zn--OH groups appeared to be a desirable feature for the solid-state synthesis of ZnO NCs that significantly decreased the decomposition temperature of crystalline precursors 3\u20135<\/b>.<\/p>\n

\"chej2015_kubiki\"<\/p>\n

Paper on Wiley Online Library website<\/a><\/p>\n

Full-text PDF<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"

Chem. Eur. J., 2015, 21, 5488\u20135495.   tert-Butyl(tert-Butoxy)zinc Hydroxides: Hybrid Models for Single Source Precursors of ZnO Nanocrystals Kamil Soko\u0142owski,a\u00a0\u00a0Iwona Justyniak,a\u00a0 Wojciech Bury,b\u00a0\u00a0 Justyna Grzonka,c\u00a0Zbigniew Kaszkur,a \u0141ukasz M\u0105kolski,b\u00a0\u00a0 Micha\u0142 Dutkiewicz,b\u00a0 Agnieszka Lewalska,b Dominik Kubicki,b\u00a0\u00a0 Katarzyna W\u00f3jcik,a\u00a0 Krzysztof Kurzyd\u0142owskic and\u00a0 Janusz Lewi\u0144ski*ab a\u00a0Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44\/52, 01-224 Warsaw, Poland b\u00a0Faculty […]<\/p>\n","protected":false},"author":2,"featured_media":3426,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"inline_featured_image":false,"footnotes":""},"categories":[19],"tags":[],"class_list":["post-3377","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-paper"],"_links":{"self":[{"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/posts\/3377","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=3377"}],"version-history":[{"count":13,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/posts\/3377\/revisions"}],"predecessor-version":[{"id":3481,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/posts\/3377\/revisions\/3481"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/media\/3426"}],"wp:attachment":[{"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=3377"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=3377"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=3377"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}