{"id":3087,"date":"2014-06-29T12:50:07","date_gmt":"2014-06-29T11:50:07","guid":{"rendered":"http:\/\/lewin.ch.pw.edu.pl\/?p=3087"},"modified":"2014-09-26T12:47:03","modified_gmt":"2014-09-26T11:47:03","slug":"toward-coordination-polymers-based-on-fine-tuneable-group-13-organometallic-phthalates","status":"publish","type":"post","link":"https:\/\/lewin.ch.pw.edu.pl\/?p=3087","title":{"rendered":"Toward Coordination Polymers Based on Fine-Tuneable Group 13 Organometallic Phthalates"},"content":{"rendered":"<div><i>Inorg. Chem.<\/i> <b>2014<\/b>, <i>53<\/i>, 7270-7275.<\/div>\n<div><\/div>\n<div><\/div>\n<p>&nbsp;<\/p>\n<div><strong><span style=\"font-size: 2em;\">Toward Coordination Polymers Based on Fine-Tuneable Group 13 Organometallic Phthalates<\/span><\/strong><\/div>\n<p><strong><a href=\"?page_id=307\">Iwona Justyniak<\/a>,<sup>*a<\/sup> <a href=\"?page_id=320\">Wojciech Bury<\/a>,<sup>b<\/sup> <a href=\"?page_id=351\">Daniel Prochowicz<\/a>,<sup>b<\/sup> <a href=\"?page_id=314\">Katarzyna W\u00f3jcik<\/a>,<sup>a<\/sup>         Janusz Zachara,<sup>b<\/sup> and <a href=\"?page_id=14\">Janusz Lewi\u0144ski<\/a>*<sup>a<\/sup><sup>b<\/sup><\/strong><\/p>\n<p><em><sup>a <\/sup>Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44\/52, 01-224 Warsaw, Poland<\/em><br \/>\n<sup>b <\/sup>Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw, Poland<\/em><\/p>\n<p><strong>DOI: <\/strong> 10.1021\/ic5005598<br \/>\nFirst published online 27 Jun 2014<\/p>\n<p>A homologue series of group 13 organometallic macrocyclic phthalates [(MMe<sub>2<\/sub>)<sub>2<\/sub>(\u03bc-O<sub>2<\/sub>C)2-1,2-C<sub>6<\/sub>H<sub>4<\/sub>]<sub>2<\/sub> (where M = Al, Ga, In) was investigated as potential molecular building blocks for crystal engineering of extended metal\u2212organic structures. Reactions of these molecular carboxylates with various monodentate Lewis bases provide the first examples of group 13 organometallic coordination polymers based on a dicarboxylate unit. <\/p>\n<p style=\"text-align: center;\"><img decoding=\"async\" class=\"aligncenter  wp-image-2004\" src=\"http:\/\/lewin.ch.pw.edu.pl\/wp-content\/uploads\/2014\/07\/inorg2014phthalates.jpg\" width=\"700\"  \/><\/p>\n<p><a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/ic5005598\" target=\"_blank\">Paper on the Publisher's website<\/a><\/p>\n<p><a href=\"http:\/\/lewin.ch.pw.edu.pl\/wp-content\/uploads\/2014\/07\/inorg2014phthalates.pdf\" target=\"_blank\">Full-text PDF<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>Inorg. Chem. 2014, 53, 7270-7275. &nbsp; Toward Coordination Polymers Based on Fine-Tuneable Group 13 Organometallic Phthalates Iwona Justyniak,*a Wojciech Bury,b Daniel Prochowicz,b Katarzyna W\u00f3jcik,a Janusz Zachara,b and Janusz Lewi\u0144ski*ab a Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44\/52, 01-224 Warsaw, Poland b Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw, [&hellip;]<\/p>\n","protected":false},"author":2,"featured_media":3097,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"inline_featured_image":false,"footnotes":""},"categories":[19],"tags":[],"class_list":["post-3087","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-paper"],"_links":{"self":[{"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/posts\/3087","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=3087"}],"version-history":[{"count":8,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/posts\/3087\/revisions"}],"predecessor-version":[{"id":3212,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/posts\/3087\/revisions\/3212"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/media\/3097"}],"wp:attachment":[{"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=3087"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=3087"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=3087"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}