{"id":2690,"date":"2014-01-07T11:56:52","date_gmt":"2014-01-07T10:56:52","guid":{"rendered":"http:\/\/lewin.ch.pw.edu.pl\/?p=2690"},"modified":"2014-04-16T14:45:21","modified_gmt":"2014-04-16T13:45:21","slug":"zinc-hydroxides-and-oxides-supported-by-organic-ligands","status":"publish","type":"post","link":"https:\/\/lewin.ch.pw.edu.pl\/?p=2690","title":{"rendered":"Zinc hydroxides and oxides supported by organic ligands"},"content":{"rendered":"<div><i>Coordination Chemistry Reviews,<\/i> <b>2014<\/b>, <i>270\u2013271<\/i>, 112\u2013126.<\/div>\n<div><\/div>\n<div><\/div>\n<p>&nbsp;<\/p>\n<div><strong><span style=\"font-size: 2em;\">Zinc hydroxides and oxides supported by organic ligands: synthesis and structural diversity<\/span><\/strong><\/div>\n<p><strong><a title=\"Daniel Prochowicz\" href=\"http:\/\/lewin.ch.pw.edu.pl\/?page_id=351\">Daniel Prochowicz<\/a>,<sup>a<\/sup> <a title=\"Kamil Soko\u0142owski\" href=\"http:\/\/lewin.ch.pw.edu.pl\/?page_id=250\">Kamil Soko\u0142owski<\/a>,<sup>b<\/sup> <a title=\"Janusz Lewinski\" href=\"http:\/\/lewin.ch.pw.edu.pl\/?page_id=14\">Janusz Lewi\u0144ski<\/a>*<sup>a<\/sup><sup>b<\/sup><\/strong><\/p>\n<p><em><sup>a\u00a0<\/sup>Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw, Poland<\/em><br \/>\n<em><sup>b\u00a0<\/sup>Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44\/52, 01-224 Warsaw, Poland<\/em><\/p>\n<p><strong>DOI: <\/strong>10.1016\/j.ccr.2013.12.003<\/strong><br \/>\nPublished online: 21 Dec 2013<\/p>\n<p>This review focuses on the synthesis, reactivity and structural chemistry of zinc hydroxides and oxides derived essentially from organozinc compounds. It demonstrates the advantages of the organometallic route to these classes of compounds that is time and atom efficient. We have surveyed the preparation of organozinc hydroxide complexes via direct hydrolysis of both R<sub>2<\/sub>Zn compounds and alkylzinc complexes of the type RZn(L) (where L = monoanionic, mono- or multidentate organic ligand). The variety of their molecular structures is discussed with an emphasis on how the character of zinc bonded alkyl substituents or L ligands can influence the stability and the mode of aggregation of the resulting zinc hydroxides. The section dedicated to synthetic procedures and the solid state structures of zinc oxides focuses on the following aspects: (i) zincoxane compounds; (ii) the encapsulation of ZnO species into organozinc moieties and (iii) zinc oxide complexes supported by organic ligands. Finally, utility of oxozinc carboxylates as a predesigned molecular platform for modelling of the reactivity of prototypical Zn-MOFs towards H<sub>2<\/sub>O and donor solvents is presented.<\/p>\n<p style=\"text-align: center;\"><img decoding=\"async\" src=\"http:\/\/lewin.ch.pw.edu.pl\/wp-content\/uploads\/2014\/01\/coorchemrev2014hydroxides.png\" width=\"550\" class=\"aligncenter size-large wp-image-2649\" \/><\/p>\n<p><a href=\"http:\/\/www.sciencedirect.com\/science\/article\/pii\/S0010854513002786\" target=\"_blank\">Paper www website<\/a><\/p>\n<p><a href=\"wp-content\/uploads\/2014\/04\/coorchemrev2014hydroxides.pdf\" target=\"_blank\">Full-text PDF<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>Coordination Chemistry Reviews, 2014, 270\u2013271, 112\u2013126. &nbsp; Zinc hydroxides and oxides supported by organic ligands: synthesis and structural diversity Daniel Prochowicz,a Kamil Soko\u0142owski,b Janusz Lewi\u0144ski*ab a\u00a0Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw, Poland b\u00a0Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44\/52, 01-224 Warsaw, Poland DOI: 10.1016\/j.ccr.2013.12.003 Published online: 21 [&hellip;]<\/p>\n","protected":false},"author":2,"featured_media":2703,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"inline_featured_image":false,"footnotes":""},"categories":[19],"tags":[],"class_list":["post-2690","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-paper"],"_links":{"self":[{"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/posts\/2690","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=2690"}],"version-history":[{"count":13,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/posts\/2690\/revisions"}],"predecessor-version":[{"id":2798,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/posts\/2690\/revisions\/2798"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/media\/2703"}],"wp:attachment":[{"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=2690"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=2690"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=2690"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}