 



{"id":2609,"date":"2013-11-14T17:24:08","date_gmt":"2013-11-14T16:24:08","guid":{"rendered":"http:\/\/lewin.ch.pw.edu.pl\/?p=2609"},"modified":"2015-01-14T14:53:16","modified_gmt":"2015-01-14T13:53:16","slug":"efficient-synthesis-of-manganese-ii-carboxylates","status":"publish","type":"post","link":"https:\/\/lewin.ch.pw.edu.pl\/?p=2609","title":{"rendered":"Efficient Synthesis of Manganese (II) Carboxylates"},"content":{"rendered":"<div><i>Dalton Trans.<\/i> <b>2014<\/b>, <i>43<\/i>, 3048-3051.<\/div>\n<div><\/div>\n<div><\/div>\n<p>&nbsp;<\/p>\n<div><strong><span style=\"font-size: 2em;\">Efficient synthesis of Manganese (II) carboxylates: From trinuclear cluster [Mn<sub>3<\/sub>(PhCO<sub>2<\/sub>)<sub>6<\/sub>(THF)<sub>4<\/sub>] to a unique [Mn(PhCO<sub>2<\/sub>)<sub>2<\/sub>]<sub>n<\/sub> chiral 3D network<\/span><\/strong><\/div>\n<p><strong><a title=\"Arkadiusz Kornowicz\" href=\"http:\/\/lewin.ch.pw.edu.pl\/?page_id=343\">Arkadiusz Kornowicz<\/a>,<sup>a<\/sup> <a title=\"Szymon Komorski\" href=\"http:\/\/lewin.ch.pw.edu.pl\/?page_id=370\">Szymon Komorski<\/a>,<sup>a<\/sup> <a title=\"Zbigniew Wr\u00f3bel\" href=\"http:\/\/lewin.ch.pw.edu.pl\/?page_id=333\">Zbigniew Wr\u00f3bel<\/a>,<sup>b<\/sup> <a title=\"Iwona Justyniak\" href=\"http:\/\/lewin.ch.pw.edu.pl\/?page_id=307\">Iwona Justyniak<\/a>,<sup>b<\/sup> Natalia Nedelko,<sup>c<\/sup> Anna \u015alawska-Waniewska,<sup>c<\/sup> Robert Balawender,<sup>b<\/sup> <a title=\"Professor\" href=\"http:\/\/lewin.ch.pw.edu.pl\/?page_id=14\">Janusz Lewi\u0144ski<\/a>*<sup>a<\/sup><sup>b<\/sup><\/strong><\/p>\n<p><em><sup>a\u00a0<\/sup>Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw, Poland<\/em><br \/>\n<em><sup>b\u00a0<\/sup>Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44\/52, 01-224 Warsaw, Poland<br \/>\n<\/em><em><sup>c<\/sup><\/em><em><sup>\u00a0<\/sup>Institute of Physics, Polish Academy of Sciences, Al. Lotnikow 32\/46, 02-668 Warsaw, Poland<\/em><\/p>\n<p><strong>DOI: <\/strong>10.1039\/C3DT53211A<br \/>\nReceived 12 Sep 2013, Accepted 14 Nov 2013<\/p>\n<p>An efficient synthetic procedure of manganese carboxylates including a trinuclear cluster [Mn<sub>3<\/sub>(PhCO<sub>2<\/sub>)<sub>6<\/sub>(THF)<sub>4<\/sub>] and unique [Mn(PhCO<sub>2<\/sub>)<sub>2<\/sub>]<sub>n<\/sub> chiral 3D network is reported. The procedure involves a simple redox process, in which acidic protons are reduced to gaseous hydrogen by oxidizing metallic manganese under solvothermal conditions.<\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" src=\"http:\/\/lewin.ch.pw.edu.pl\/wp-content\/uploads\/2013\/11\/dalton2013_mn-1024x512.png\" alt=\"dalton2013_mn\" width=\"650\" height=\"325\" class=\"aligncenter size-large wp-image-2649\" srcset=\"https:\/\/lewin.ch.pw.edu.pl\/wp-content\/uploads\/2013\/11\/dalton2013_mn-1024x512.png 1024w, https:\/\/lewin.ch.pw.edu.pl\/wp-content\/uploads\/2013\/11\/dalton2013_mn-300x150.png 300w\" sizes=\"auto, (max-width: 650px) 100vw, 650px\" \/><\/p>\n<p><a href=\"http:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2013\/dt\/c3dt53211a#!divAbstract\" target=\"_blank\">Paper on RSC website<\/a><\/p>\n<p><a href=\"wp-content\/uploads\/2015\/01\/dalton2013_mn.pdf\" target=\"_blank\">Full-text PDF<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>Dalton Trans. 2014, 43, 3048-3051. &nbsp; Efficient synthesis of Manganese (II) carboxylates: From trinuclear cluster [Mn3(PhCO2)6(THF)4] to a unique [Mn(PhCO2)2]n chiral 3D network Arkadiusz Kornowicz,a Szymon Komorski,a Zbigniew Wr\u00f3bel,b Iwona Justyniak,b Natalia Nedelko,c Anna \u015alawska-Waniewska,c Robert Balawender,b Janusz Lewi\u0144ski*ab a\u00a0Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw, Poland b\u00a0Institute of Physical Chemistry, [&hellip;]<\/p>\n","protected":false},"author":2,"featured_media":2652,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"inline_featured_image":false,"footnotes":""},"categories":[19],"tags":[],"class_list":["post-2609","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-paper"],"_links":{"self":[{"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/posts\/2609","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=2609"}],"version-history":[{"count":14,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/posts\/2609\/revisions"}],"predecessor-version":[{"id":3396,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/posts\/2609\/revisions\/3396"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/media\/2652"}],"wp:attachment":[{"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=2609"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=2609"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=2609"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}