{"id":2396,"date":"2013-10-14T14:44:06","date_gmt":"2013-10-14T13:44:06","guid":{"rendered":"http:\/\/lewin.ch.pw.edu.pl\/?p=2396"},"modified":"2013-12-06T16:35:08","modified_gmt":"2013-12-06T15:35:08","slug":"permanent-porosity-derived-from-the-self-assembly-of-highly-luminescent-molecular-zinc-carbonate-nanoclusters","status":"publish","type":"post","link":"https:\/\/lewin.ch.pw.edu.pl\/?p=2396","title":{"rendered":"Hungry, Hungry Micropores"},"content":{"rendered":"
Angew. Chem. Int. Ed.<\/i> 2013<\/strong> 52<\/i>, 13414-13418.<\/div>\n
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 <\/p>\n

Permanent Porosity Derived From the Self-Assembly of Highly Luminescent Molecular Zinc Carbonate Nanoclusters<\/span><\/strong><\/div>\n

Kamil Soko\u0142owski<\/a>,a<\/sup> Wojciech Bury<\/a>,b<\/sup> Iwona Justyniak<\/a>,a<\/sup> David Fair\u00e9n-Jim\u00e9nez,c<\/sup> Katarzyna So\u0142tys<\/a>,a<\/sup> Daniel Prochowicz<\/a>,b<\/sup> Sihai Yang,d<\/sup> Martin Schr\u00f6derd<\/sup> and Janusz Lewi\u0144ski<\/a>*a<\/sup>b<\/sup><\/strong><\/p>\n

a <\/sup>Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44\/52, 01-224 Warsaw, Poland<\/em>
\nb <\/sup>Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw, Poland<\/em>
\nc <\/sup>Department of Chemical Engineering & Biotechnology, University of Cambridge, Pembroke Street, Cambridge CB2 3RA, United Kingdom<\/em>
\nd <\/sup>School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD, United Kingdom<\/p>\n

DOI: <\/strong> 10.1002\/anie.201306785
\nReceived 02 Aug 2013, Accepted 4 Sep 2013
\nFirst published online 14 Oct 2013<\/p>\n

Hungry hungry micropores:<\/strong> Reaction of [Zn4<\/sub>(\u03bc3<\/sub>-OH)2<\/sub>(L)4<\/sub>(t<\/i>Bu)2<\/sub>] (LH = 8-hydroxyquinoline) with CO2<\/sub> forms a 3D microporous material with spherical zinc carbonate nanoclusters packed in a diamondoid manner in the solid state. This compound exhibits one of the highest Brunauer\u2014Emmett\u2014Teller surface areas for a noncovalent porous material, with high H2<\/sub>, CO2<\/sub>, and CH4<\/sub> uptake. <\/p>\n

\"anie2013hungry_micropores\"<\/p>\n

Paper on the Publisher's website<\/a><\/p>\n

Full-text PDF<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"

Angew. Chem. Int. Ed. 2013 52, 13414-13418.   Permanent Porosity Derived From the Self-Assembly of Highly Luminescent Molecular Zinc Carbonate Nanoclusters Kamil Soko\u0142owski,a Wojciech Bury,b Iwona Justyniak,a David Fair\u00e9n-Jim\u00e9nez,c Katarzyna So\u0142tys,a Daniel Prochowicz,b Sihai Yang,d Martin Schr\u00f6derd and Janusz Lewi\u0144ski*ab a Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44\/52, 01-224 Warsaw, Poland b […]<\/p>\n","protected":false},"author":2,"featured_media":2420,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"inline_featured_image":false,"footnotes":""},"categories":[19],"tags":[],"class_list":["post-2396","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-paper"],"_links":{"self":[{"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/posts\/2396","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=2396"}],"version-history":[{"count":20,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/posts\/2396\/revisions"}],"predecessor-version":[{"id":2674,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/posts\/2396\/revisions\/2674"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/media\/2420"}],"wp:attachment":[{"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=2396"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=2396"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=2396"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}