{"id":2336,"date":"2013-10-02T18:39:56","date_gmt":"2013-10-02T17:39:56","guid":{"rendered":"http:\/\/lewin.ch.pw.edu.pl\/?p=2336"},"modified":"2013-10-15T16:50:35","modified_gmt":"2013-10-15T15:50:35","slug":"probing-secondary-coordination-sphere-influence-on-the-oxygenation-of-zinc-alkyls","status":"publish","type":"post","link":"https:\/\/lewin.ch.pw.edu.pl\/?p=2336","title":{"rendered":"Probing secondary coordination sphere influence on the oxygenation of zinc alkyls"},"content":{"rendered":"<div><i><strong>Chem. Commun.<\/strong><\/i>, 2013, <strong>49<\/strong>, 10477-10479.<\/div>\n<div><\/div>\n<div><\/div>\n<div><strong><span style=\"font-size: 2em;\"><br \/>\nProbing secondary coordination sphere influence on the oxygenation of zinc alkyls: formation of a unique zinc peroxide species<\/span><\/strong><\/div>\n<p>&nbsp;<br \/>\n<strong>Piotr Sobota,*<sup>a<\/sup>   Rafa\u0142 Petrus,<sup>a<\/sup>   <a href=\"?page_id=317\">Karolina Zelga<\/a>,<sup>b<\/sup>   <a href=\"?page_id=376\">\u0141ukasz M\u0105kolski<\/a>,<sup>b<\/sup> <br \/>  <a href=\"?page_id=382\">Dominik Kubicki<\/a><sup>b<\/sup>   and   <a href=\"?page_id=14\">Janusz Lewi\u0144ski<\/a>*<sup>b<\/sup><sup>c<\/sup><\/strong><\/p>\n<p><sup>a <\/sup>Faculty of Chemistry, University of Wroc\u0142aw, 14 F. Joliot-Curie St., 50-383 Wroc\u0142aw, Poland<br \/>\n<sup>b <\/sup>Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw, Poland<br \/>\n<sup>c <\/sup>Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44\/52, 01-224 Warsaw, Poland<\/p>\n<p><strong>DOI: <\/strong> 10.1039\/C3CC46206D<br \/>\nReceived 13 Aug 2013, Accepted 17 Sep 2013<br \/>\nFirst published online 17 Sep 2013<\/p>\n<p>Reactions of ethylzinc derivatives of o-hydroxybiphenyl with O2 were investigated. The study revealed an essential role in the oxygenation process of intra-molecular interactions involving aromatic rings and provided a unique aryloxide (hydroxide) Zn8(OAr)8(OH)6(O2) cluster with an encapsulated peroxide species.<\/p>\n<p style=\"text-align: center;\"><img decoding=\"async\" class=\"aligncenter  wp-image-2004\" alt=\"chemcomm2013_peroxides\" src=\"http:\/\/lewin.ch.pw.edu.pl\/wp-content\/uploads\/2013\/10\/chemcomm2013_peroxides.jpg\" width=\"400\" \/><\/p>\n<p><a href=\"http:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2013\/cc\/c3cc46206d\" target=\"_blank\">Paper on RSC website<\/a><\/p>\n<p><a href=\"http:\/\/lewin.ch.pw.edu.pl\/wp-content\/uploads\/2013\/10\/chemcomm2013_peroxides.pdf\" target=\"_blank\">Full-text PDF<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>Chem. Commun., 2013, 49, 10477-10479. Probing secondary coordination sphere influence on the oxygenation of zinc alkyls: formation of a unique zinc peroxide species &nbsp; Piotr Sobota,*a Rafa\u0142 Petrus,a Karolina Zelga,b \u0141ukasz M\u0105kolski,b Dominik Kubickib and Janusz Lewi\u0144ski*bc a Faculty of Chemistry, University of Wroc\u0142aw, 14 F. Joliot-Curie St., 50-383 Wroc\u0142aw, Poland b Faculty of Chemistry, [&hellip;]<\/p>\n","protected":false},"author":2,"featured_media":2342,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"inline_featured_image":false,"footnotes":""},"categories":[19],"tags":[],"class_list":["post-2336","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-paper"],"_links":{"self":[{"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/posts\/2336","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=2336"}],"version-history":[{"count":11,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/posts\/2336\/revisions"}],"predecessor-version":[{"id":2484,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/posts\/2336\/revisions\/2484"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/media\/2342"}],"wp:attachment":[{"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=2336"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=2336"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=2336"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}