{"id":1944,"date":"2013-04-18T17:53:59","date_gmt":"2013-04-18T16:53:59","guid":{"rendered":"http:\/\/lewin.ch.pw.edu.pl\/?p=1944"},"modified":"2013-10-14T16:45:34","modified_gmt":"2013-10-14T15:45:34","slug":"activation-of-co2-by-tbuznoh-species-efficient-routes-to-novel-nanomaterials-based-on-zinc-carbonates","status":"publish","type":"post","link":"https:\/\/lewin.ch.pw.edu.pl\/?p=1944","title":{"rendered":"Efficient routes to novel nanomaterials based on zinc carbonates"},"content":{"rendered":"
Chem. Commun.<\/i>, 2013<\/strong>, 49<\/i>, 5271-5273.<\/div>\n
<\/div>\n
<\/div>\n

 <\/p>\n

Activation of CO<\/span>2<\/sub><\/small> by <\/span>t<\/em>BuZnOH species: efficient routes to novel nanomaterials based on zinc carbonates<\/span><\/strong><\/div>\n

Kamil Soko\u0142owski<\/a>,a<\/sup>\u00a0\u00a0 Wojciech Bury<\/a>,b<\/sup>\u00a0\u00a0 Iwona Justyniak<\/a>,a<\/sup>\u00a0\u00a0 Anna M. Cie\u015blak<\/a>,a<\/sup>\u00a0\u00a0 Ma\u0142gorzata Wolska<\/a>,b<\/sup>\u00a0\u00a0 Katarzyna So\u0142tys<\/a>,a<\/sup>\u00a0\u00a0 Igor Dzi\u0119cielewski<\/a>c<\/sup>\u00a0and\u00a0\u00a0 Janusz Lewi\u0144ski<\/a>*a<\/sup>b<\/sup><\/strong><\/p>\n

a\u00a0<\/sup>Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44\/52, 01-224 Warsaw, Poland<\/em>
\nb\u00a0<\/sup>Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw, Poland<\/em>
\nc\u00a0<\/sup>Institute of High Pressure Physics Unipress, Polish Academy of Sciences, Sokolowska 29\/37, 01-142 Warsaw, Poland<\/em><\/p>\n

DOI: <\/strong> 10.1039\/C3CC41639A
\nReceived 04 Mar 2013, Accepted 18 Apr 2013
\nFirst published online 18 Apr 2013<\/p>\n

We report on the activation of CO2<\/sub><\/small>\u00a0by the well-defined alkylzinc hydroxide (t<\/em>BuZnOH)6<\/sub><\/small>\u00a0in the absence and presence of\u00a0t<\/em>Bu2<\/sub><\/small>Zn as an external proton acceptor. The slight modifications in reaction systems involving organozinc precursors enable control of the reaction products with high selectivity leading to the isolation of the mesoporous solid based on ZnCO3<\/sub><\/small>\u00a0nanoparticles or an unprecedented discrete alkylzinc carbonate [(t<\/em>BuZn)2<\/sub><\/small>(\u03bc5<\/sub><\/small>-CO3<\/sub><\/small>)]6<\/sub><\/small>\u00a0cluster with the Zn\u2013C bond intact, respectively.<\/p>\n

\"chemcomm2013_CO2\"<\/p>\n

Paper on RSC website<\/a><\/p>\n

Full-text PDF<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"

Chem. Commun., 2013, 49, 5271-5273.   Activation of CO2 by tBuZnOH species: efficient routes to novel nanomaterials based on zinc carbonates Kamil Soko\u0142owski,a\u00a0\u00a0 Wojciech Bury,b\u00a0\u00a0 Iwona Justyniak,a\u00a0\u00a0 Anna M. Cie\u015blak,a\u00a0\u00a0 Ma\u0142gorzata Wolska,b\u00a0\u00a0 Katarzyna So\u0142tys,a\u00a0\u00a0 Igor Dzi\u0119cielewskic\u00a0and\u00a0\u00a0 Janusz Lewi\u0144ski*ab a\u00a0Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44\/52, 01-224 Warsaw, Poland b\u00a0Faculty of Chemistry, Warsaw […]<\/p>\n","protected":false},"author":2,"featured_media":2010,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"inline_featured_image":false,"footnotes":""},"categories":[19],"tags":[],"class_list":["post-1944","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-paper"],"_links":{"self":[{"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/posts\/1944","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=1944"}],"version-history":[{"count":27,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/posts\/1944\/revisions"}],"predecessor-version":[{"id":2438,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/posts\/1944\/revisions\/2438"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=\/wp\/v2\/media\/2010"}],"wp:attachment":[{"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=1944"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=1944"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/lewin.ch.pw.edu.pl\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=1944"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}